Cu、As和Sn对低合金钢连铸坯第Ⅲ脆性区的影响

Effect of Cu,As and Sn on the low ductility region Ⅲ of low alloy steel continuous casting slabs

  • 摘要: 为了研究残余元素Cu、As和Sn对钢高温延塑性的影响,采用Gleeble-1500热模拟试验机测试了含有一定量Cu、As和Sn低合金钢连铸坯的高温延塑性,得到了低合金钢第Ⅲ脆性温度区在920~730℃之间.结果表明:第Ⅲ脆性温度区脆化的主要原因是奥氏体单相区低温域钢中Cu、As和Sn等残余元素在奥氏体晶界的偏聚削弱晶界结合能,导致试样沿晶脆性断裂;奥氏体和铁素体两相区在原奥氏体晶界析出的网状铁素体导致试样沿晶开裂.钢中的Cu、As和Sn元素增加第Ⅲ脆性温度区的宽度和脆性凹槽的深度,同时提高第Ⅲ脆性温度区的上限临界温度.

     

    Abstract: To investigate the effect of residual elements Cu, As and Sn on the hot ductility of steels, the hot ductility of low alloy steel continuous casting slabs containing some Cu, As and Sn was measured by tensile tests with a Gleeble-1500 tensile test machine. It is found that the low ductility region Ⅲ is between 920 and 730℃. Embrittlement in the region Ⅲ is caused by Cu, As and Sn segregation along the austenite intergranular in the austenite single-phase low-temperature range, which weakens the binding energy of the intergranular and induces brittle fracture along the intergranular; the precipitation of proeutectoid ferrite film along the austenite intergranular in the austenite and ferrite two-phases range induces intergranular cracks. Cu, As and Sn in the steel increase the width and depth of the low ductility region In and enhance its upper limit critical temperature.

     

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